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brightness_autoPeace be upon you and God's mercy and blessings.
Grand Ayatollah Sayyid Khamenei (may God protect him):
If the tissue is considered paper (which is what is written on), it is permissible to prostrate on it if it is made from wood or plants other than cotton or linen.
This applies to commonly used paper tissues, and it is permissible to prostrate on them.
Therefore, there is no need to inform him of anything; his prayer is valid in any case.
Source: Educational Message, What is Permissible to Prostrate On + Office of His Eminence in Lebanon.
Grand Ayatollah Sayyid Sistani (may God protect him):
It is not permissible to prostrate on paper tissues (Kleenex) unless it is confirmed that they are made from materials on which prostration is valid. It is permissible to prostrate on paper if it is known to be made from permissible materials, or from cotton or linen, but it is not permissible if there is doubt.
You should inform him if he is unaware of the ruling, as it is obligatory to teach the ignorant.
Source: Official website: 1, 2.
May you be successful in all good.